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- The new dz2 and dx2-y2 orbitals do not have as the head contact as the ligands form of fit earlier or slip by such orbitals, hence reducing the electron-electron repulsion plus the time of one’s orbital.
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Inside the equipment of one’s smaller Planck constant ħ, all of the dust one to relocate 3 size provides either integer twist and you may follow Bose-Einstein statistics otherwise half of-integer twist and you can follow Fermi-Dirac analytics. Because the bromo ligand are a failing career ligand , that it molecule is actually highest spin. The newest breaking from tetrahedral complexes is personally opposite regarding the brand new breaking of one’s octahedral buildings. Recall one to inside octahedral complexes, the fresh dz2 and you will dx2-y2 orbitals have high time compared to dxz, dxy, and you will dyz orbitals. Inside the tetrahedral buildings, the contrary happen while the dxz, dxy, and dyz orbitals provides highest time versus dz2 and you can dx2-y2 orbitals.
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